转炉一般用以下脱氧剂:Fe-Mn、Fe-Si、Mn-Si合金、Ca-Si合金、铝、Fe-Al、复合脱氧剂。脱氧剂的使用应在保证钢质量的前提下,选用价格便宜的铁合金,以降低钢的成本。
(1)用Si/Mn脱氧,形成的脱氧产物可能有:固相的纯SiO2;液相的MnO?SiO2;固溶体MnO-FeO。通过控制合适的ω〔Mn〕/ω〔Si〕比,能得到液相的MnO?SiO2产物,夹杂物易于上浮排除。(2)用S+Mn十Al脱氧,形成的脱氧产物可能有蔷薇辉石(2MnO?A1203?5Si02);www.yejinluliao.com 硅铝榴石(3MnO?Al2O3?3SiO2);A12O3(ω〔Al2O3〕>30%)。控制夹杂物成分在低熔点范围,为此钢中ωIAl]≤0.006%,钢中[O)溶可达0.0020%(20ppm)而无Al203沉淀,钢水可浇性好,不堵水口,铸坯不会产生皮下气孔。
(3)用过量铝脱氧。对于低碳铝镇静钢,钢中酸溶铝[Al]s含量为0.02%~0.04%,则脱氧产物全部为Al203。Al203熔点高达2050℃,在钢水中呈固态;若Al203含量多钢水的可浇性变差,易堵水口。另外,Al203为不变形夹杂物,影响钢材性能。通过吹氩搅拌加速Al203上浮排出,或者喂入Si-Ca线、 Ca线的钙处理,改变Al203性态。[Al]s含量较低,钙处理生成低熔2CaO?Al203?Si02;对于低碳铝镇静钢,通过钙处理产物易于上浮排除纯净了钢水,改善了可浇性 The?general?with the following:?Fe-Mn,?Fe-Si?deoxidizing agent,?Mn-Si?alloy,?Ca-Sialloy,?aluminum,?Fe-Al,?compound deoxidizer. The use of?deoxidizing agent?provided that the?quality of steel,?iron?alloy?with?cheap price,?in order to reduce?the cost of steel. (1)?with Si /?Mn deoxidation,?deoxidization?product formation?may be:?solid phase?pure SiO2;?liquid?phase of MnO?SiO2?solid solution MnO-FeO.?By controlling appropriate?ω(Mn)?/?(Si) ratio To get?MnO in the liquid phase,?SiO2 products,?inclusion float easily?excluded.?(2)?with S+Mn ten?Al deoxidation,?deoxidization?product formation?may have?Rhodonite?(2MnOA1203?5Si02); Silicon aluminum?garnet?(3MnO?Al2O3?3SiO2);?A12O3?(ω?(Al2O3) >30%). Control of inclusion composition in low melting point range, therefore the steel?ω IAl] ≤ 0.006 Steel?in?solution?[O)?up to 0.0020%?(20ppm)?and no Al203?precipitation,?castability,?noclogging nozzle?produce?blowhole,?billet?not. (3)?with an excess of?aluminum deoxidation.?For low?carbon aluminum?killed steel,?acid soluble aluminium in steel?[Al]s?content is 0.02% ~?0.04%,?the?deoxidation?products are?Al203.?The melting point of Al203?was as high as 2050?℃, In molten steel?is solid;?if the?Al203 content in?steel?can be poured?variation,?easyclogging nozzle. In addition,?Al203?non deforming inclusion,?the impact of steel?performance.?Byblowing argon stirring?accelerated Al203?floatation,?or?feeding?Si-Ca?wire, Calcium treatment?Ca line,?change the Al203?property.?Low level of [Al]s,?calcium treatment?to generate?low melting?2CaO?? Al203 ??Si02;?for low?carbon aluminum killed steel,?through?calcium treatment The product is easy to?float?out of?pure?molten steel,?improve the?castability